XmlmmCIF equivalent: phasing_MIR_der
Data items in the PHASING_MIR_DER category record details
about individual derivatives used in the phasing of the
structure when methods involving isomorphous replacement are
involved.
A derivative in this context does not necessarily equate with
a data set; for instance, the same data set could be used to
one resolution limit as an isomorphous scatterer and to a
different resolution (and with a different sigma cutoff) as an
anomalous scatterer. These would be treated as two distinct
derivatives, although both derivatives would point to the same
data sets via _phasing_MIR_der.der_set_id and
_phasing_MIR_der.native_set_id.
XmlmmCIF equivalent: phasing_MIR_der/R_cullis_acentric
Residual factor R~cullis,acen~ for acentric reflections in this
derivative.
The Cullis R factor was originally defined only for centric
reflections. It is, however, also a useful statistical
measure for acentric reflections, which is how it is used in
this data item.
sum| |Fph~obs~ +/- Fp~obs~| - Fh~calc~ |
R~cullis,acen~ = --------------------------------------------------------------
sum|Fph~obs~ - Fp~obs~|
Fp~obs~ = the observed structure factor amplitude of the native
Fph~obs~ = the observed structure factor amplitude of the
derivative
Fh~calc~ = the calculated structure factor amplitude from the
heavy atom model
sum is taken over the specified reflections
Ref: Cullis, A. F., Muirhead, H., Perutz, M. F., Rossmann, M. G.
& North, A. C. T. (1961). Proc. Roy. Soc. A265, 15-38.
XmlmmCIF equivalent: phasing_MIR_der/R_cullis_anomalous
Residual factor R~cullis,ano~ for anomalous reflections in this
derivative.
The Cullis R factor was originally defined only for centric
reflections. It is, however, also a useful statistical
measure for anomalous reflections, which is how it is used in
this data item.
This is tabulated for acentric terms. Any value <1.0 means
there is some contribution to the phasing from the anomalous
data.
sum| |Fph+~obs~Fph-~obs~ - Fh+~calc~ - Fh-~calc~| |
R~cullis,ano~ = ------------------------------------------------------------------------------
sum|Fph+~obs~ - Fph-~obs~|
Fph+~obs~ = the observed positive Friedel structure factor
amplitude for the derivative
Fph-~obs~ = the observed negative Friedel structure factor
amplitude for the derivative
Fh+~calc~ = the calculated positive Friedel structure factor
amplitude from the heavy atom model
Fh-~calc~ = the calculated negative Friedel structure factor
amplitude from the heavy atom model
sum is taken over the specified reflections
Ref: Cullis, A. F., Muirhead, H., Perutz, M. F., Rossmann, M. G.
& North, A. C. T. (1961). Proc. Roy. Soc. A265, 15-38.
XmlmmCIF equivalent: phasing_MIR_der/R_cullis_centric
Residual factor R~cullis~ for centric reflections in this
derivative.
sum| |Fph~obs~ +/- Fp~obs~| - Fh~calc~ |
R~cullis~ = ----------------------------------------------------------------
sum|Fph~obs~ - Fp~obs~|
Fp~obs~ = the observed structure factor amplitude of the native
Fph~obs~ = the observed structure factor amplitude of the
derivative
Fh~calc~ = the calculated structure factor amplitude from the
heavy atom model
sum is taken over the specified reflections
Ref: Cullis, A. F., Muirhead, H., Perutz, M. F., Rossmann, M. G.
& North, A. C. T. (1961). Proc. Roy. Soc. A265, 15-38.
XmlmmCIF equivalent: phasing_MIR_der/d_res_high
The highest resolution for the interplanar spacing in the
reflection data used for this derivative. This is the smallest
d value.
XmlmmCIF equivalent: phasing_MIR_der/d_res_low
The lowest resolution for the interplanar spacing in the
reflection data used for this derivative. This is the highest
d value.
XmlmmCIF equivalent: phasing_MIR_der/der_set_id
The data set that was treated as the derivative in this
experiment.
This data item is a pointer to _phasing_set.id in the
PHASING_SET category.
XmlmmCIF equivalent: phasing_MIR_der/details
A description of special aspects of this derivative, its data,
its solution, or its use in phasing.
XmlmmCIF equivalent: phasing_MIR_der/native_set_id
The data set that was treated as the native in this
experiment.
This data item is a pointer to _phasing_set.id in the
PHASING_SET category.
XmlmmCIF equivalent: phasing_MIR_der/number_of_sites
The number of heavy atom sites in this derivative.
XmlmmCIF equivalent: phasing_MIR_der/power_acentric
The mean phasing power P for acentric reflections in this
derivative.
sum|Fh~calc~^2^|
P = (------------------------------------------------)^1/2^
sum|Fph~obs~ - Fph~calc~|^2^
Fph~obs~ = the observed structure factor amplitude of this
derivative
Fph~calc~ = the calculated structure factor amplitude of this
derivative
Fh~calc~ = the calculated structure factor amplitude from the
heavy atom model
sum is taken over the specified reflections
XmlmmCIF equivalent: phasing_MIR_der/power_centric
The mean phasing power P for centric reflections in this
derivative.
sum|Fh~calc~^2^|
P = (-----------------------------------------------)^1/2^
sum|Fph~obs~ - Fph~calc~|^2^
Fph~obs~ = the observed structure factor amplitude of the
derivative
Fph~calc~ = the calculated structure factor amplitude of the
derivative
Fh~calc~ = the calculated structure factor amplitude from the
heavy atom model
sum is taken over the specified reflections
XmlmmCIF equivalent: phasing_MIR_der/reflns_acentric
The number of acentric reflections used in phasing for this
derivative.
XmlmmCIF equivalent: phasing_MIR_der/reflns_anomalous
The number of anomalous reflections used in phasing for this
derivative.
XmlmmCIF equivalent: phasing_MIR_der/reflns_centric
The number of centric reflections used in phasing for this
derivative.
XmlmmCIF equivalent: phasing_MIR_der/reflns_criteria
Criteria used to limit the reflections used in the phasing
calculations.
XmlmmCIF equivalent: phasing_MIR_der/id
The value of _phasing_MIR_der.id must uniquely identify
a record in the PHASING_MIR_DER list.
Note that this item need not be a number; it can be any unique
identifier.